Cairenn
Senior Member.
I am also a clay artist and the reactions of chemicals at temperatures is an important part of ceramics. This discusses a problem with sulfur coming out of clay in a glaze firing.
The gases are generated from carbon and sulfur in the clay components of the body. As a natural part of the weathering and deposit of clay particles, organic materials containing carbon and sulfur settle throughout the clays we mine and use for modern ceramics. When these organic materials reach temperatures ranging from 1290° to 1650° Fahrenheit, they combine with oxygen, form gases, escape the clay body through the pores, and exhaust from the kiln. Under optimal conditions, all of the organics will be expelled from the clay through this process during the bisque firing. However, it is possible to leave carbon and sulfur in the clay under the following two circumstances.
First, the bisque firing can be too fast. Not only must the firing go to or beyond 1650°, but it must allow enough time for the maximum quantity of carbon to burn out. The process is not instantaneous; it takes time for all the carbons and sulfurs to combine with oxygen, and it takes time for the subsequent gases to work their way out of the body.
Second, the atmosphere in the bisque kiln can be oxygen poor. If this is the case, some of the organics will remain in the body because they can find no oxygen with which to combine. We see this phenomenon in both gas and electric kilns. In electric kilns with poor ventilation and tightly packed ware, the organics in the clay quickly combine with what little oxygen is available, and there is no means for new oxygen to get to the pots. Gas kilns have good ventilation, but that does not mean that oxygen is available. If too much reduction is used in the 1290° to 1650° range, the atmosphere will be oxygen poor and carbon and sulfur will be left behind.