Hitstirrer
Active Member
Thank you. Its possible that I am right then. lol.
Based on past experience noThank you. Its possible that I am right then. lol.
ok sorry i didn't know to explain the video as niels harrit obviously can explain better than i can
Thanks for actually bringing up the points on your own, so they can be discussed.ok sorry i didn't know to explain the video as niels harrit obviously can explain better than i can
the theory is that nanothermite was used in combination with thermite, the thermite used to cut through the steel and the nanothermite either as an explosive.
The DSC shows a rapid release of energy more so than known nanothermite samples, this means its more advanced or better not that is not thermite. The energy is released more rapidly than the known nanothermite tests from LANL , the energy peaks in the graph meaning its released quickly, organic compounds and epoxy paints release their energy at a flate rate the graphs in DSCs have shown to be flat meaning the energy released is at a constant rate.
Sol gel is added to the nanothermite in order to add gases to the explosion thus giving it more of an explosive effect it also hold the stuff together.
In the niels harrrit paper it shows elemental aluminium, either millete didn't test the correct red stuff or he didn't properly separate the aluminium from the iron oxide, further testing should be done I think .
either millete didn't test the correct red stuff or he didn't properly separate the aluminium from the iron oxide
Undeniably true. A clue might be that Chemistry isn't a sub-branch of Rhetoric.You can't just take Harrit's word for it, you have to learn about the chemistry.
And Logic precedes Rhetoric too.What happened to all the primer paint?
I tried to find the Millete paper but couldn't find any XEDS spectra or any BSE images of what he was testing exactly. Maybe I had the wrong link could you provide the paper ?External Quote:The next XEDS spectrum (Fig. 17 ) was acquired from a
region that showed a high concentration of aluminum. Using
a conventional quantification routine, it was found that the
aluminum significantly exceeded the oxygen present (approximately
a 3:1 ratio). Thus, while some of the aluminum
may be oxidized, there is insufficient oxygen present to account
for all of the aluminum; some of the aluminum must
therefore exist in elemental form in the red material. This is
an important result. Aluminum particles are covered with a
layer of aluminum oxide irrespective of size, thus it is reasonable
to find a significant oxygen content with the aluminum,
given the very high surface area to volume ratio of
these very fine particles.
Why has no one else tested the dust ? Why doesn't the scientific community want to do any experiments with the 911 dust ? More testing should be done , a lot more , problem is getting the scientific community to do testing or become interested in testing the wtc dust ! No one seems to care ..
External Quote:Claiming to have found the chips, Millette perfomed an XEDS analysis for elemental composition but failed to do any of the other tests including BSE, DSC, the flame test, the MEK test, or measurement of the chip resistivity. Having inexplicably "ashed" the chips at 400 °C in a muffle furnace, thereby proving that they were not the materials of interest (which ignite at 430 °C), Millette ignored the remainder of the study he had set out to replicate. Because he did not do the DSC test, he could not do XEDS of the spheres formed from the chips. Since he had still not found spheres in the dust, he could not test those and this allowed him to ignore the testing of spheres from the thermite reaction.
You don't have to be an expert in "nano chemistry". Just a reasonable ability to be logical should suffice.Im not an expert in nano chemistry, niels harrit is, so maybe you should email him with your questions, I only did chemistry at university what are your qualifications you seem to know a bit and I'm sure niels harrit could answer some of these questions for you.
External Quote:Claiming to have found the chips, Millette perfomed an XEDS analysis for elemental composition but failed to do any of the other tests including BSE, DSC, the flame test, the MEK test, or measurement of the chip resistivity. Having inexplicably "ashed" the chips at 400 °C in a muffle furnace, thereby proving that they were not the materials of interest (which ignite at 430 °C), Millette ignored the remainder of the study he had set out to replicate. Because he did not do the DSC test, he could not do XEDS of the spheres formed from the chips. Since he had still not found spheres in the dust, he could not test those and this allowed him to ignore the testing of spheres from the thermite reaction.
Go for it!External Quote:
We observe that the total energy released from some of the red chips exceeds the theoretical limit for thermite alone (3.9 kJ/g). One possibility is that the organic material in the red layer is itself energetic. Determination of the chemical compound(s) involved in the organic component of the red material would promote understanding. Further studies of the red material (separated from the gray material) compared to known super-thermite variants using DSC, TGA, FTIR (etc.) analyses would certainly be in order. In particular, NMR and GC-mass spectroscopy and related studies are urged to iden- tify the organic material.
We have observed that some chips have additional ele- ments such as potassium, lead, barium and copper. Are these significant, and why do such elements appear in some red chips and not others? An example is shown in Fig. (31) which shows significant Pb along with C, O, Fe, and Al and displays multiple red and gray layers.
In addition, the gray-layer material demands further study. What is its purpose? Sometimes the gray material ap- pears in multiple layers, as seen in Fig. (32).
The red-mesoporous material is on the left in this view, with the touching dark-gray layer next and a lighter-gray material on the right as seen in a photograph of the same chip (right hand image in Fig. (32)). The gray layer in con- tact with the red layer has the XEDS spectrum shown in Fig. (33) in which iron is not seen, while the outer gray material had an XEDS spectrum just like those displayed in Fig. (6).
Thus, the middle-layer gray material contains carbon and oxygen and presumably also contains hydrogen, too light to be seen using this method. Since the gray inner layer appears between two other layers, it may be a type of adhesive, bind- ing a red porous thermitic material to another, iron-rich ma- terial. One might speculate that the red thermitic material has been attached to rusty iron by an adhesive. The cooling ef- fect of the iron in such close proximity, acting as a heat sink, might quench the reaction and explain the fact that unreacted red thermitic material, always found by us in thin layers, remains in the dust. These hypotheses invite further experiments.
Millette did not set out to replicate, or even refute, the Harrit study.
Really? His bio reads 'organic photochemistry and photophysics, including the photophysics of nanostructures and the structural dynamics of photochemical processes'Im not an expert in nano chemistry , niels harrit is
It was proof that the organic material (epoxy) gives off an exotherm. Any 'thermitic material' in the mix didn't contribute much, since there was only a tiny amount of it.DSC wasn't proof it was thermite it was proof its energetic
XEDS spectra of red chips.6% where did you get this from
'Nanostructured Energetic Materials with Sol-Gel Methods' Gash et al. 2003Do you have a source for the stoichiometric ratio of LANL sol gels ?
This comment seems quite confused, frankly. First off, can you describe what 'the primer paint' of the WTC was? That would help to start with.Dr millete was not able to identify it as what paint has both a red side and a grey side with nano sized plates connected to each other? It doesn't match the paint primer in the wtc as well , its just a mystery stuff that is unidentified kaolin'' like'' but not the primer paint of the wtc.
Other scientists have done so. They include Marc Basile and FH Couannier. You should read this thread, since your questions are answered already elsewhere.Why has no other scientists tried to replicate the experiment ?
That's fine. Funny that AE911Truth, which pulled in $549,000 in 2012, cannot spend a couple of grand to get those tests done on Harrit's dust samples. It doesn't seem like either Harrit or Richard Gage are the least bit interested in further tests, does it?Mark Basille is trying to get a blind study of the material so that the scientists who test it don't know where it came from and test it for what it is .
http://www.markbasile.org
That's what they claim, yes. They tried to infer it, but their tests are not conclusive. They said they would perform more conclusive tests, that was almost 5 years ago.....From the bentham paper after soaking for 55 hours elemental aluminium was found.
It can be found hereI tried to find the Millete paper but couldn't find any XEDS spectra or any BSE images of what he was testing exactly. Maybe I had the wrong link could you provide the paper ?
Maybe there was no thermite there. Use Occam's Razor once in awhile to cut thru the nonsense.c) Maybe there was a protective layer or perhaps it wasn't visible to the eyewitnesses as it was on the steel beams which weren't visible as they were inclosed, I'm not aware of any survivors on the floors of the jets impact.
Wow, you really like to shift the responsibility off their shoulders, don't you? They are making the claims, it's their job to present. And besides, how do you know they haven't been invited? You're making that up. You don't know.The scientific community haven't invited them to any conferences I'm sure they would be very eager to go and present their evidence and have others replicate the results.
It would help if Harrit et al. had submitted the paper to a major chemistry or science journal, instead of Bentham Open. It would help if Harrit et al. would present their hypothesis outside of the truther community - and in the scientific community instead.More testing should be done , a lot more , problem is getting the scientific community to do testing or become interested in testing the wtc dust ! No one seems to care ..
Millette was financed by a fund raising effort from JREF members. They were so rabid in their desire to debunk Harrit that they threw cash at him to finance his work. To now say that Millette's paymasters specifically tasked him not to replicate or refute the Haritt paper is so much bunk that I'm astonished that you have the cheek to write that. An opportunity for Millette to 'peer review' Harrits work by duplicating his tests, and then move on to other 'vital' tests that were being demanded by JREF -- and he wasn't asked to do that by JREF ?
I leave readers to come to their own conclusion.
In the same way the exploration of nanomaterials is irrelevant as there is no real evidence that any kind of superthermite was present;
Alienentity said:...there are simply some inconclusive tests by the proponents of that hypothesis followed by other conclusive tests showing the hypothesis to be false.
Alienentity said:Even worse, the thermitists actual hypothesis posits that the explosive would have to be painted on, very thinly, onto the steel!
Alienentity said:This proposal is not only untested and unproven,...
Alienentity said:it simply doesn't exist in the history of demolition!
Alienentity said:There are mountains of validation required for this theory to be even remotely plausible to a serious and discerning scientific audience.
Alienentity said:The work hasn't even begun, and yet the thermitist cult has turned the idea into an almost religious belief.
Alienentity said:There should be absolutely no leeway given to the thermitists, and no 'new investigation', until they have met the expected scientific standards, the burden of proof. It would be dangerously foolish to do otherwise.
Alienentity said:Really, I guess you could say I agree there needs to be new investigation - by Jones et al. to properly identify their chips. Why do they continue to avoid this due diligence?
Really? His bio reads 'organic photochemistry and photophysics, including the photophysics of nanostructures and the structural dynamics of photochemical processes'
His PhD is in Mechanistic Photochemistry. That is about 'organic photochemical reactions.
He's no specialist in thermitic compounds, particularly nanothermites. This should be obvious to a fair observer, as he and his team had no experience with such materials, and are speculating based on a couple of papers by Tillotson and Gash. Seriously, those papers are available for you to read.yea , niels harrit has published 56 peer reviewed and has a masters in chemistry , how many papers have you published, and what are your qualifications.
It was proof that the organic material (epoxy) gives off an exotherm. Any 'thermitic material' in the mix didn't contribute much, since there was only a tiny amount of it.an epoxy doesn't give off an exotherm like the one seen in the DSC… otherwise all paint would be explosive
XEDS spectra of red chips.from the harrit study ?, it clearly showed the ratio of iron to oxygen and aluminium you would expect.
'Nanostructured Energetic Materials with Sol-Gel Methods' Gash et al. 2003Read the entire report did not find the ratio … thanks .. it was actually interesting
In milletes report is states that the material doesn't match any of the 166 epoxies in the wtc so why are you asking me what it was?
It doesn't contain zinc either so its not paint primer.
All these have reasonable explanations which have already been mentioned without any challenge from you.It is a willful act of ignorance to try to keep these pieces of evidence from forming a theory in your head. Couple them with the broader unexplained phenomena, (vaporized lead, molten molybdenum, the WPI steel, thermal imaging from NASA showing temps in excess of 1300C weeks later, numerous photos, video and reports of molten metal, blast phenomena, numerous reports of explosions, the vast amount of unaccounted-for microspheres in the dust, the list goes on...) and suddenly it becomes crazy to deny that these events and evidences could be connected.
This is not proper debate at all, but something foreign to the very spirit of this site.
niels harrit has published 56 peer reviewed and has a masters in chemistry , how many papers have you published, and what are your qualifications.
Please prove that claim by comparing to other DSC exotherms. Oh, you can't.an epoxy doesn't give off an exotherm like the one seen in the DSC… otherwise all paint would be explosive
This is just mad raving now. There were not 166 epoxies used, Millette was just trying to cross reference with the known Tnemec formulations.In milletes report is states that the material doesn't match any of the 166 epoxies in the wtc so why are you asking me what it was?
It doesn't contain zinc either so its not paint primer.
Nice try at deflection. How many papers on nano composite materials has Niels Harrit published? Please let us know.
Please prove that claim by comparing to other DSC exotherms. Oh, you can't.
The DSC can't show you whether something is explosive or not. That's not what it does. This is a common thermitist misunderstanding.
It just gives you the decomp of the material as it's heated. You haven't got a clue what you're talking about.
This is just mad raving now. There were not 166 epoxies used, Millette was just trying to cross reference with the known Tnemec formulations.
You're not even trying to understand the subject.
You thermitists have a terrible situation now - you deny that there are any paint chips at all - everything has now become nanothermite to you.
But that means that neither Millette's or FH Couannier's 'nanothermite' is really nanothermite, so the most likely reality is that Harrit's is not nanothermite either.
It's not hard to see why your hypothesis is getting no traction in the scientific world; it's not sensible or scientific. You say no zinc = no paint.
We say if there's no elemental Al, especially only trace amounts if at all, then no thermite.
One of us is wrong. But we know for a fact there was paint in the WTC. The odds are very much in my favour. I'm not worried at all about upcoming tests - but you should be.
That's their claim, it has not been reproduced, rather it has been falsified. It is indeed a willful act of ignorance to ignore the work of Dr Millette in this instance.Except the XEDS mapping data which showed both Fe2O3 and elemental Al,
No matter how many times you write it, it still isn't true: a DSC is done at a very slow rate, you're not burning anything. You can't tell if something is thermitic from a DSC test. Sorry, you just can't. But you keep right on believing, it's reassuring to me since it means your hypothesis is wrong and there wasn't a giant overarching conspiracy using super secret materials to blow up the towers. I sleep better knowing that it's just a hardcore fringe of thermitists who are going to keep tilting at that particular windmill, no matter what.the DSC test which demonstrated a sharp exotherm at about 450C
Ignition? Did you say ignition? What was the peak temperature then? Did anyone measure it? Uhm, no they didn't.and the by-products of this ignition which were iron microspheres very much like the ones found in the WTC dust,
Sorry, science doesn't work that way. The Harrit claims have never been replicated, even by other truthers. They are not confirmed in a standard scientific way, no.The tests were not only conclusive, they were cross-corroborated.
I can't make crazy people sane, no. You're right. You will continue to believe in stuff that never happened.Your denial of this does not make it go away. It just shows you have no interest in an honest discussion about this.
Likely a testing error, or contamination. It has not been replicated. So far it hasn't stood the basic scientific standard of corroboration by other scientists working independently.Why are the XEDS maps they made that show a separation between the Al and Si not good enough for you?
Nonsense. The pigment in LaClede is to stop corrosion. The job of fire protection was given to SFRM, and sprinkler systems, as in all other steel construction of late.Also, it's worth noting that you don't dispute that LeClede and Tnemec are both ceramic coatings (when baked as the Tnemec was).
No, we don't. You think they aren't, but that doesn't matter to reality.We both know the red-gray chips aren't paint.
And the argument that "it's TOO ENERGETIC to be nano-thermite" do not help your cause. The theory, as it stands (as I'm understanding and presenting it) is that this stuff was highly-engineered in a high-tech lab. It's use was as a thermal bridge. Possibly the idea was that no matter what level the "event" happened on the buildings, this stuff would set in motion a chain reaction of events that would normally need a high-temp reaction to set in motion. Other explosives/incendiaries were probably in play in this theory. But, (now pay heed) I DON'T KNOW how this stuff was actually used. What can be said is that it bridges temps from below a bic lighter to above the melting point of iron. Probably much hotter in abundance. How hot? I do not know. But it ain't paint.
External Quote:When Dr Farrer burned epoxy paint in the DSC, it gave a very broad thermal trace, NOT at all like the spiked exothermic DSC peak in our Fig 19. This is one of the many tests he did to check things.
http://911blogger.com/news/2012-09-08/letter-regarding-redgray-chip-analysesExternal Quote:You say that the exothermic peaks we observed in the DSC (our Figure 19) could be due to burning of epoxy paint. Not according to our experiments -- that is, when Dr Farrer burned epoxy paint in the DSC, it gave a very broad thermal trace, NOT at all like the spiked exothermic DSC peaks in Fig 19. Igniting paint in the same DSC is one of many tests performed to double-check our experiments, and I urge you to do similar tests.
Table 1. Composition of Primer Paint on the World Trade Center Towers according to T. F. Sramek16External Quote:We did TEM analysis also, years ago now, but we did not see any titanium in the red/gray chips! (Referring specifically to the clean-surface chips; see Figs. 6 and 7 in our published paper.) More and more, it appears that Millette was simply not looking at the same material that we studied.
Doesn't contain zinc so is not the wtc primer paint … So its not primer paint either then where did this paint come from?
Perhaps it came from the undercoat of a veteran child's toy on someone's bookshelf.
Are you saying that is so beyond the realm of possibility it's akin to unhinged fantasy?
Or is it an actual plausible possibility? Why do you object to it?
External Quote:Table 1. Composition of Primer Paint on the World Trade Center Towers according to T. F. Sramek16
Pigment
Vehicle
- Iron Oxide 35.9%
- Zinc Yellow (Zinc Chromate13) 20.3%
- Tnemec pigment (proprietary composition) 33.7%
- Diatomaceous silica 10.1%
- Soya alkyd resin solids 16.5%
- Hard Resin 2.8%
- Raw Linseed Oil 35.1%
- Bodied Linseed Oil 6.4%
- Suspension agents 2.2%
- Driers and antiskin 4.8%
- Thinners 32.3%