As you say, a very small background content of such spheres is normally present in dust in industrial areas where steelwork such as you describe has occured over years. But that is normally less than 0.5%.
source?
Whereas the dust in Manhattan after 9/11 was nearer to 6%.
Ah - so that would appear to be the
RJ Lee report prepared for the Deutch Bank - available here??
they compared "normal" dust as being from a "normal office" - not an industrial site. they found iron sphere's to comprise about 0.04% of it (table 3 of the reference, page 24)
So, saying that it was 'not indicative of anything in particular' goes against RJ Lee's opinion who were very surprised at the % seen.
And they said they were expected byproducts.
External Quote:
Particles of materials that had been modified by exposure to high temperature, such as spherical particles of iron and silicates, are common in WTC Dust because of the fire that accompanied the WTC Event, but are not common in "normal" interior office dust.
(page 5)
In fact they came to use that as a 'marker' to identify 9/11 dust samples from all others.
Microspheres of various substances were ONE of the characteristics of "9/11 dust" compared with normal office dust - the microsphere materials included iron, zinc, lead and silicates.
there were other markers of 9/11 dust - including
Chrysotile asbestos
mineral wool
Gypsum
partially burned or melted plastic
Its both the unusual % seen and the fact that it was almost pure iron that is the mystery - not that some microspheres can exist in a city built from steel.
no - neither the volume nor the composition were a mystery in the RJ Lee report.
they make no comment at all about the purity of the iron microspheres that I can see - their comment about iron is this:
External Quote:
2.3.5 Heat affected particulate and combustion products
Particles that either were formed as a consequence of high temperature or were modified by exposure to high temperature are important WTC Dust Markers for WTC Dust. Fires that were a part of the WTC Event produced combustion-modified products that traveled with other components of WTC Dust. Considering the high temperatures reached during the destruction of the WTC, the following three types of combustion products would be expected to be present in WTC Dust. These products are:
• Vesicular carbonaceous particles primarily from plastics
• Iron-rich spheres from iron-bearing building components or contents
• High temperature aluminosilicate from building materials
(Page 16 - my emphasis added)
External Quote:
Various metals (most notably iron and lead) were melted during the WTC Event, producing spherical metallic particles. Exposure of phases to high heat
results in the formation of spherical particles due to surface tension.
Figure 21 and Figure 22 show a spherical iron particle resulting from the
melting of iron (or steel).
(page 17)
and
External Quote:
In addition to the spherical iron and aluminosilicate particles, a variety of heavy metal particles including lead, cadmium, vanadium, yttrium, arsenic, bismuth, and barium particles were produced by the pulverizing, meltingand/or combustion of the host materials such as solder, computer screens, and paint during the WTC Event
(page 19)
they compared "normal" dust as being from a "normal office" - not an industrial site. they found iron sphere's to comprise about 0.04% of it (table 3 of the reference, page 24)
the "9/11" dust also had vastly more mineral wool, vermiculite, gypsum, chrysolite, and a lot less "Class C" particles defined as "common building background particles" (page 23)
The report summary states:
External Quote:
2.5 Summary
The differences within the WTC Dust and typical background dusts include the fineness and evidence of heat, the size and concentration of the chrysotile, and the length and concentration of the mineral wool and other fibers, as well as the frequency of occurrence of spherical particles produced by fire and heat, char and soot, and other building products.
Iron doesn't even rate a specific mention - being covered by the reference to "spherical particles"
In the report the analysis of the various materials found is always found to be consistent with the makeup of the building and its contents, and the temperatures that were involved.
To put it in simple terms - the dust composition was as expected.