Waste reduction
Actinides Half-life Fission products
244Cm 241Puƒ 250Cf 227Ac№ 10–22 y medium m is
meta 85Kr 113mCd₡
232Uƒ 238Pu 243Cmƒ 29–90 y 137Cs 90Sr 151Sm₡ 121mSn
ƒ for
fissile 249Cfƒ 242mAmƒ 251Cfƒ[23] 140 y –
1.6 ky
No fission products
have a half-life in the
range of 91 y – 210 ky
241Am 226Ra№[24] 247Bk
240Pu 229Th 246Cm 243Am 5–7 ky
4n 245Cmƒ 250Cm 239Puƒ 8–24 ky
236Npƒ 233Uƒ 230Th№ 231Pa№ 32–160 ky
248Cm 4n+1 234U№ 211–348 ky 99Tc ₡ can capture 126Sn 79Se
236U 237Np 242Pu 247Cmƒ 0.37–23 My 135Cs₡ 93Zr 107Pd 129I long
244Pu № for
NORM 4n+2 4n+3 80 My 6-7% 4-5% 1.25% 0.1-1% <0.05%
232Th№ 238U№ 235Uƒ№ 0.7–14 Gy fission product yield[25]
Nuclear waste became a greater concern by the 1990s. Breeding fuel cycles attracted renewed interest because of their potential to reduce actinide wastes, particularly plutonium and minor actinides.[6] After the spent nuclear fuel has been removed from a light water reactor for longer than 100,000 years, these transuranics would be the main source of radioactivity. Eliminating them would eliminate much of the long-term radioactivity from the spent fuel.[7]
In principle, breeder fuel cycles can recycle and consume all actinides,[4] leaving only fission products. As the graphic in this section indicates, fission products have a peculiar 'gap' in their aggregate half-lives, such that no fission products have a half-life longer than 91 years and shorter than two hundred thousand years. As a result of this physical oddity, after several hundred years in storage the waste's radioactivity would drop to the low level of the long-lived fission products. However, this benefit requires highly efficient separation of transuranics from spent fuel. If the fuel reprocessing methods used leave a large fraction of the transuranics in its final waste stream, this advantage would be reduced.[3]
Both types of breeding cycles can reduce actinide wastes:
The fast breeder reactor's fast neutrons can fission actinide nuclei with even numbers of both protons and neutrons. Such nucleii usually lack the low-speed "thermal neutron" resonances of fissile fuels used in LWRs.[26]
The thorium fuel cycle inherently produces lower levels of heavy actinides. The fertile material in the thorium fuel cycle has an atomic weight of 232, while the fertile material in the uranium fuel cycle has an atomic weight of 238. That mass difference means that thorium-232 requires six more neutron capture events per nucleus before the transuranic elements can be produced. In addition to this simple mass difference, the reactor gets two chances to fission the nuclei as the mass increases: First as the effective fuel nuclei U233, and as it absorbs two more neutrons, again as the fuel nuclei U235.[27][28]
A reactor whose main purpose is to destroy actinides, rather than increasing fissile fuel stocks, is sometimes known as a burner reactor. Both breeding and burning depend on good neutron economy, and many designs can do either. Breeding designs surround the core by a breeding blanket of fertile material. Waste burners surround the core with non-fertile wastes to be destroyed. Some designs add neutron reflectors or absorbers.